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Vapor permeation membrane module.

VP · Technology

Vapor Permeation

Vapor permeation runs the same dense membrane chemistry as pervaporation, but on a vapor-phase feed. That means lower mass transfer resistance and higher fluxes, with the trade-off that the feed must be vaporized first. Used where the feed is already in the vapor phase (reactor exhaust, dryer offgas) or where the highest possible flux is needed.

What it solves

Performance you can size against.

The outcomes below come from commissioned systems and verified pilots, not theoretical limits. Every number is independently testable on your own feed.

VOC capture from process exhaust
>98%
Recovers solvents from reactor and dryer offgas at ambient pressure.
Higher flux than pervaporation
2 to 5x
Compact systems for high-throughput applications.
Compatible with existing process
No need to condense and re-vaporize; we tap directly into vapor lines.

How it works

The working principle.

A vapor feed is fed across the membrane at low pressure. The target component sorbs into the dense membrane and diffuses across. A vacuum or chilled sweep on the permeate side condenses the recovered fraction. Non-permeating components return to process or vent.

Performance envelope

Specs and operating range.

For preliminary sizing only. Production sizing is always validated against your specific feed.

Operating temperature
60 to 120°C
Operating pressure
1 to 3bar absolute
Solvent capture rate
>98%
Permeate purity
>99.5wt%
Flux vs pervaporation (same membrane)
2 to 5x
Specific energy
80 to 150kWh/m³ feed equivalent
Membrane life (typical)
2 to 4years

How we compare

VP vs the alternatives.

Where Vapor Permeation wins, where it does not, and where the alternatives are honestly the better fit.

Feed phase

Vapor Permeation

Vapor (taps directly into vapor lines)

Pervaporation

Liquid (requires liquid feed)

Activated Carbon Recovery

Either, but vapor preferred

Flux

Vapor Permeation

High (2 to 5x pervaporation)

Pervaporation

Moderate

Activated Carbon Recovery

N/A (batch capture, not flux)

Recovery for reuse

Vapor Permeation

>98%, recovered as condensate

Pervaporation

>98%, recovered as condensate

Activated Carbon Recovery

Bed regeneration recovers most; quality varies

Continuous operation

Vapor Permeation

Yes

Pervaporation

Yes

Activated Carbon Recovery

No (load and regenerate cycles)

Best fit

Vapor Permeation

Reactor exhaust, dryer offgas, high-throughput VOC capture

Pervaporation

Liquid solvent dehydration, azeotrope breaking

Activated Carbon Recovery

Low-volume, intermittent VOC streams

Engineering FAQ

Questions engineers ask.

The questions we hear weekly. If you have a different one, send it with your consultation request and we will answer it directly.

When should I use vapor permeation over pervaporation?
When the feed is already in vapor phase (reactor exhaust, dryer offgas) or when flux is the binding constraint. Vapor permeation runs 2 to 5x faster than pervaporation on the same membrane chemistry, so it makes high-throughput compact systems possible.
Can it handle hot, dirty exhaust streams?
Yes, with pretreatment. We add cyclone separators and condensate knockout upstream to drop entrained particulates and condensables. The membrane runs hot (60 to 120°C) but it does not tolerate liquid carryover.
What is the minimum VOC concentration that makes economic sense?
Typically 0.5% by volume in the vapor stream. Below that, the energy to maintain the recovery loop exceeds the value of the recovered solvent. We pilot the specific stream to confirm.
Can vapor permeation be combined with pervaporation?
Yes, often in a hybrid. Pervaporation does the bulk water removal from a liquid solvent; vapor permeation polishes the vapor stage to azeotrope-breaking purity. We design hybrids when the customer's spec requires both bulk and final purity in one system.

Have a feed that VP
might fit?

We will pilot before we promise. Send us a sample and a target outcome. If the technology fits, we will tell you what to expect; if it does not, we will tell you that too.