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Industrial water treatment with crystallization equipment.

ZLD · Technology

Zero Liquid Discharge

Zero liquid discharge is not a single technology; it is a system architecture. Petro Sep engineers ZLD trains that combine reverse osmosis and AQUA-SEP® vacuum membrane distillation with crystallization to deliver compliant systems where every drop of water is recovered and the only output is solid waste. We pilot the full train on real feed before any capex commitment.

What it solves

Performance you can size against.

What the process delivers. Every number is testable on your own feed.

Liquid discharge
Zero
Permit-ready for jurisdictions with strict discharge limits.
Water recovery
98 to 99.5%
Returned to the process loop or polished to discharge.
Electricity vs evaporator + crystallizer
26 vs 43
kWh/m³ for a 100 GPM unit, with 129 vs 300 kWh/m³ of utilities, on Petro Sep's AQUA-SEP® Energy Comparison data sheet.

How it works

The working principle.

ZLD trains stage separation by feed concentration. Membrane stages handle dilute and mid-range feeds at low energy. Thermal stages take the final brine to dryness. The result: every kg of dissolved solid leaves the plant as solid, every kg of water leaves as recovered liquid.

Performance envelope

Specs and operating range.

For preliminary sizing only. Production sizing is always validated against your specific feed.

Final solids
Solid only
Water recovery
98 to 99.5%
Specific energy, AQUA-SEP route
26 + 129kWh/m³ electricity + utilitiesAQUA-SEP® Energy Comparison data sheet (100 GPM unit), against 43 + 300 kWh/m³ for an evaporator and crystallizer.
Footprint
Modular, scales to site
Stages (typical)
3 to 5
Membrane stage recovery
85 to 95%
Thermal stage feed concentration
20 to 30wt% TDS

How we compare

ZLD vs the alternatives.

Where Zero Liquid Discharge wins, where it does not, and where the alternatives are honestly the better fit.

Architecture

Petro Sep ZLD

Membrane + thermal hybrid (RO + VMD + crystallization)

All-Evaporation ZLD

Steam-driven evaporation + crystallization throughout

Crystallization-Only Discharge

Single-stage crystallizer on a partial stream

Specific energy

Petro Sep ZLD

26 kWh/m³ electricity plus 129 kWh/m³ utilities on the AQUA-SEP® route (data sheet, 100 GPM unit)

All-Evaporation ZLD

43 kWh/m³ electricity plus 300 kWh/m³ utilities for an evaporator and crystallizer (same data sheet)

Crystallization-Only Discharge

Per-unit volume cost is high; only practical at small scale

Capex

Petro Sep ZLD

Mid

All-Evaporation ZLD

High

Crystallization-Only Discharge

Low (incomplete recovery)

Water recovery

Petro Sep ZLD

98 to 99.5%, returned to process

All-Evaporation ZLD

98 to 99.5%, returned to process

Crystallization-Only Discharge

Not a true ZLD

Best fit

Petro Sep ZLD

Mining, oil-and-gas, large industrial wastewater (cost-sensitive ZLD)

All-Evaporation ZLD

Where membrane fouling is intractable

Crystallization-Only Discharge

Small streams, supplementary treatment

Engineering FAQ

Questions engineers ask.

The questions we hear weekly. If you have a different one, send it with your consultation request and we will answer it directly.

What feeds suit a Petro Sep ZLD train?
Anything where you need to discharge zero liquid and the feed has dissolved or suspended solids in the 1 to 25 wt% range. Lower than that, simple RO concentrate is enough; higher and the membrane stages contribute less.
How is membrane fouling managed in a ZLD train?
Stage-specific cleaning regimes, with feed pretreatment tuned to each stage's chemistry. The dilute stages run cleaner; the concentrated stages get more aggressive CIP. We design with fouling in mind from the bench validation onward.
What are the solid outputs?
Mixed salts, recovered as flowable cake or powder depending on crystallizer type. For some streams, the solids are saleable (gypsum, sodium sulfate); for others, they go to landfill. We characterize the solids in the pilot phase.
Can ZLD systems run on waste heat?
The membrane stages, yes; the crystallizer needs higher-grade heat (steam). Many of our ZLD trains are partially waste-heat-driven on the front end and steam-driven on the back end. The membrane front-end is what makes the whole train cheaper to operate.

Have a feed that ZLD
might fit?

We will pilot before we promise. Send us a sample and a target outcome. If the technology fits, we will tell you what to expect; if it does not, we will tell you that too.